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Coherent dynamical recoupling of diffusion-driven decoherence in magnetic resonance | Phys. Rev. Lett. 111, 080404 (2013)

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Coherent dynamical recoupling of diffusion-driven decoherence in magnetic resonance

Gonzalo A. Álvarez, Noam Shemesh, and Lucio Frydman
Department of Chemical Physics, Weizmann Institute of Science, Rehovot, 76100, Israel
Received 13 May 2013; published 20 August 2013

During recent years, dynamical decoupling (DD) has gained relevance as a tool for manipulating and interrogating quantum systems. This is particularly relevant for spins involved in nuclear magnetic resonance (NMR), where DD sequences can be used to prolong quantum coherences, or to selectively couple or decouple the effects imposed by random environmental fluctuations. In this Letter, we show that these concepts can be exploited to selectively recouple diffusion processes in restricted spaces. The ensuing method provides a novel tool to measure restriction lengths in confined systems such as capillaries, pores or cells. The principles of this method for selectively recoupling diffusion-driven decoherence, its standing within the context of diffusion NMR, extensions to the characterization of other kinds of quantum fluctuations, and corroborating experiments, are presented.

© 2013 American Physical Society

via Phys. Rev. Lett. 111, 080404 (2013): Coherent Dynamical Recoupling of Diffusion-Driven Decoherence in Magnetic Resonance.

arXiv: [1305.2794] Coherent dynamical recoupling of diffusion-driven decoherence in magnetic resonance.

Time evolution of the spin magnetization under CPMG (N = 8 pulses) and Hahn-echo sequences for spins diffusing in a restricted space (circles, triangles), and under free diffusion (crosses, dashes). The solid black lines show the time range where the restricted diffusion effects dominate; the difference ∆M_SDR between these lines gives a contrast, over which signals can be coherently modulated by a suitable Selective Dynamical Decoupling (SDR) filter function.
Time evolution of the spin magnetization under CPMG (N = 8 pulses) and Hahn-echo sequences for spins diffusing in a restricted space (circles, triangles), and under free diffusion (crosses, dashes). The solid black lines show the time range where the restricted diffusion effects dominate; the difference ∆M_SDR between these lines gives a contrast, over which signals can be coherently modulated by a suitable Selective Dynamical Decoupling (SDR) filter function.
Experimental SDR signals normalized with the first data point (symbols) as a function of the x delays of the SDR sequence. The solid lines are analytical fittings of our model to the experimental curve. By using the measured diffusion coefficient D0 ∼ 2.3 × 10−5 cm^2/s, the fitted diameter d given in the plots is in agreement with the nominal value d = 5 ± 1μm.
Experimental SDR signals normalized with the first data point (symbols) as a function of the x delays of the SDR sequence. The solid lines are analytical fittings of our model to the experimental curve. By using the measured diffusion coefficient D0 ∼ 2.3 × 10−5 cm^2/s, the fitted diameter d given in the plots is in agreement with the nominal value d = 5 ± 1μm. The behavior of the SDR curves resemble the root mean square displacement of the diffusing spins in a restricted space: in both cases curves plateu for times x larger than the correlation time characteristic of achieving a restricted diffusion regime, evidence a full sampling of the restricting space.
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